Photophysical properties and Energy transfer Dye Laser (ETDL) characteristics of a new dye:
7-DiethylAmino Coumarin with a Heteroaryl substitution in the 3-position (DACH), are presented.
The suitability of DACH as a laser dye has been verified on the basis of the absorption and
fluorescence characteristics in aprotic solvents. The dye laser characteristics of the dye pumped by
the available nitrogen laser have been successfully investigated in dimethylsulfoxide by energy transfer
dye laser mechanism, using coumarin 1 as a donor dye. DACH has been found to lase in the
blue-green region of the visible spectrum. The experimental and theoretical values of energy transfer
rate constant (kET) and the critical transfer distance (R0) have been calculated in two different solvents
to determine the nature of energy transfer. The results indicate the dominance of resonance transfer
in this ETDL.