2024
DOI: 10.1021/acs.jpcb.4c00767
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Study of Intrachain Charge Transfer in a Blue Emissive Polyfluorene Random Copolymer

Gopa Sardar,
Abhinav Biswas,
Shivam Singh
et al.

Abstract: Photophysics of a blue light-emitting fluorescent random copolymer, consisting of arylated polydioctylfluorene (aryl-F8), polydioctylfluorene (F8), and amine comonomers in a ratio of 80:15:5 is reported. In a solution of 10 −6 M, solvatochromism in absorption and photoluminescence (PL) is observed with an increased lifetime of PL as the polarity of the solvent increases. Dual fluorescence is observed in the 10 −9 M diluted solution, comprising a structured emission from a localized state in the aryl-F8 comonom… Show more

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