During the osmotic dehydration (OD) of fruit, the cell membrane displays a high resistance to mass transfer, thereby reducing the dehydration rate. To reduce thermal damage to cell membranes, alternative methods have recently been introduced to reduce the initial moisture content and/or modify the structure of fruit tissue. The aim of this work was to evaluate the effects of an ultrasound (US) pretreatment for OD on the effective diffusion coefficients and to observe the changes in the molecular structure of 'Starking' apple cubes by Fourier-transform infrared spectroscopy (FTIR) during a 3 h process using a 45°Bx sucrose solution at 60°C. In the pretreatment step, apple samples were immersed in an ultrasonic bath at 45 kHz for 20 min. The effective diffusion coefficients for water (D ew ) and solids (D es ) were calculated from the observed osmotic kinetics according to Fick's second law for the transient state. The solids coefficients were higher than the water coefficients in both processes due to the concentration difference (D e = 7.7 × 10 -9 and 9.7 × 10 -9 m 2 s -1 for OD US ). The structural changes were determined by FTIR by measuring the molecular vibration frequency for sucrose. The 1,500-900 cm -1 region of the infrared spectra was used to monitor the effect of sucrose concentration on fruit structure. We observed that the first bonds formed were C-H and C-O-C stretching (at 920 and 1,129 cm −1 , respectively) in the sucrose skeleton and glycoside bonds among sucrose molecules. The water concentration affected the diffusion coefficient significantly due to its dependence on the physical structure of the food.Additional key words: cavitation; dehydration kinetics; effective diffusion coefficient; molecular structure; solid gain; water loss.
Resumen Efectos del ultrasonido y cambios estructurales durante la deshidratación osmótica de manzana (Malus domestica Borkh) 'Starking'Durante la deshidratación osmótica (DO), la membrana celular representa una alta resistencia a la transferencia de masa y reduce la velocidad de deshidratación. Recientemente, para reducir el daño térmico de las membranas, se han considerado métodos alternativos para reducir el contenido de humedad inicial o modificar la estructura del tejido de la fruta. El objetivo de este trabajo fue evaluar el efecto del ultrasonido (US), cuando se usa como pretratamiento a la DO, sobre los coeficientes de difusión efectiva y observar los cambios en la estructura molecular de manzana 'Starking', mediante espectroscopía infrarroja por transformadas de Fourier (FTIR), durante 3 h de proceso con una solución de sacarosa a 45°Bx y 60°C. Como pretratamiento las muestras fueron tratadas en un baño ultrasónico, a 45 kHz por 20 min. Los coeficientes de difusión efectiva para agua (D ew ) y sólidos (D es = 7,7 × 10 -9 y 9,77 × 10 -9 m 2 s -1 para DO US ) fueron calcu-