Manganese (Mn) is
considered an important, energy-critical metal
due to its leading role in the production of electrochemical energy
storage devices. One valuable source of Mn is hyperaccumulator plants
used for the phytoremediation of contaminated soil. In this study,
stems and leaves of ginger (
Zingiber officinale
), which accumulate Mn at moderate levels (∼0.2 wt %) and
potassium (K) at high levels (>5 wt %), were analyzed to assess
the
potential of recovering metals from this plant. The extraction behaviors
of Mn and K were studied using raw and ash samples (100–600
°C). It was crucial to set an appropriate incineration temperature
(300 °C) to selectively extract K (∼96%) and Mn (∼90%)
using water and nitric acid over two consecutive steps. Additionally,
citric acid, a cost-effective and environmentally friendly solvent,
was just as effective (∼85%) as nitric acid in extracting Mn.
X-ray absorbance near-edge spectroscopy and X-ray diffraction analysis
of the ash before and after extractions were applied to elucidate
the extraction mechanism. The results revealed that selective extraction
of both compounds was possible due to the change in the oxidative
state of Mn(II) (soluble in water) into Mn(III) and Mn(IV) (insoluble
in water) during sample incineration. Simultaneously, there were complex
reactions associated with the changes within potassium carbonate
compounds; however, these did not affect the K extraction efficiency.