For efficient nickel recovery from laterite nickel ore,
an improved
understanding of the solubility in ternary MgCl2–NiCl2–H2O systems is required. Herein, the stable
phase equilibria in a ternary MgCl2–NiCl2–H2O system at 303, 313, and 323 K were studied
using an isothermal dissolution equilibrium method. For this ternary
system, the solubility and density were measured at different temperatures.
The equilibrium solid phases were identified using X-ray diffraction,
combined with the Schreinemakers’ method for wet residues.
Based on the solubility data, the phase diagrams of the MgCl2–NiCl2–H2O system at 303, 313,
and 323 K were plotted. At all investigated temperatures, the phase
diagrams of this ternary system presented an invariant point, two
isothermal dissolution curves, and three crystallization regions.
Neither double salt nor solid solution was produced. The Mixed Solvent
Electrolyte (MSE) model was applied to calculate the solubility for
this ternary system. According to the comparison of phase diagram,
the calculated data were in good agreement with the experimental values.