Study of surface tension and surface properties of binary systems of DMSO with long chain alcohols at various temperatures

Bagheri, Ahmad; Abolhasani, Amir; Moghadasi, Afshin; Nazari-Moghaddam, A.A.; Alavi, Seyed Abolhasan

doi:10.1016/j.jct.2013.04.009

Cited by 33 publications

(5 citation statements)

References 31 publications

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“…For dimethyl sulfoxide the values agree well with the Jasper data (72J1) (maximum bubble pressure) and with the data sets 2013BAG1 (Du Noüy ring) and 2013GEP1 (pendant drop). Conversely, the data set 2000TSI1 (Du Noüy ring) exhibits lower values than our data, and data set 1999KIN1 (stalagmometer) follows a different temperature dependence.…”

Section: Resultssupporting

confidence: 86%

On the Use of Probe Liquids for Surface Energy Measurements

Oosterlaken,

van den Bruinhorst,

de With

2023

Langmuir

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To assess the surface energy of solids, normally a set of probe liquids comprising polar and apolar compounds is used.Here we survey the surface tension of some frequently used probe liquids as given in the literature, for which a significant scatter appears to be present, and compare them with experimentally determined values. We discuss the influence of the liquid purity as well as the contact angle between the liquid and the Wilhelmy plate, which is commonly used for surface tension measurements. For hygroscopic polar probe liquids such as dimethyl sulfoxide, ethylene glycol, and formamide, water impurities appear to be of limited importance. Similarly, the amount of halogen impurities is of minor importance for diiodomethane and 1-bromonaphthalene, which decompose under the influence of light. Conversely, the influence of the contact angle for liquids that do not fully wet the plate, such as diiodomethane, is large in many cases, rendering a rather accurate determination of the contact angle necessary. Some discrepancies in the literature are indicated, and brief recommendations for future studies using such liquids are given.

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Section: Resultssupporting

confidence: 86%

On the Use of Probe Liquids for Surface Energy Measurements

Oosterlaken,

van den Bruinhorst,

de With

2023

Langmuir

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“…Thus, surface tension can be used as solubility parameter for 2D materials and solvents, in which the appropriate surface tension of solvents with high solubility is around at 40 mJ m −2 for MoS 2 23. As shown in Table 2 , surface tension of DMSO (41.1 mJ m −2 ), DMF (37.1 mJ m −2 ), and NMP (40 mJ m −2 ) were close to that of MoS 2 (44 mJ m −2 ) 23–25. In addition, DMF would more likely be attached to 2D materials surface 14.…”

Section: Charge Density and Carrier Mobility Before And After Dopingmentioning

confidence: 86%

Controllable Doping of Transition‐Metal Dichalcogenides by Organic Solvents

Sun

Guo

et al. 2020

Adv Elect Materials

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Seeking controllable and efficient surface dopant molecules for transition‐metal dichalcogenides (TMDCs) is highly valuable for fully understanding TMDCs properties and their applications to relevant devices. The general doping effect of solvents on TMDCs are explored. By selecting suitable solvents with optimized relevant factors, controllable n‐doping of molybdenum disulfide (MoS2) is obtained on the same device with the sheet density of electrons increased from 2.3 × 1011 to 6.4 × 1012, 9.7 × 1012, and 1.6 × 1013 by use of dimethylsulfoxide, N,N‐dimethylformamide, and N‐methyl‐pyrrolidone (NMP), respectively. The doping principle is explained by charge‐donating characteristics of molecule and dipole interaction. After doping by NMP, the contact resistance is reduced by four times, and the on/off current ratio of fabricated top‐gated MoS2 transistors is increased by 3 orders of magnitude. This work can guide the selection of suitable solvents for effective doping of two‐dimensional materials and advance the development of precise controllable electronic and optoelectronic devices.

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“…However, increasing the number of chains reduces surfactant solubility in aqueous solutions, and therefore, it was not possible to dissolve them in water. To examine the surface activity of these materials, DMSO, which is a polar solvent with a relatively high surface tension (γ = 42 mN m −1 ) 58 and a dielectric constant (ε) of 49, was chosen. Both double-chain surfactants were readily soluble in DMSO.…”

Section: = −mentioning

confidence: 99%