Due
to recent changes in regulatory discharge limits, selenium
removal from electric utility wastewaters is becoming an important
issue. In this work, Mg–Al–CO3 layered double
hydroxide (LDH) in granular form was evaluated for treatment of selenium-containing
groundwater in small scale column tests. The LDH material showed good
capacity for removing selenate from groundwaters that contained very
high levels of sulfate and total dissolved solids. Column tests were
investigated using the granular LDH to treat groundwater containing
trace levels of selenium <2 ppb. Removal of sulfate using chemical
pretreatment of the groundwater resulted in about 3× higher selenium
loading onto the granular LDH. The structural changes in the media
after exhaustion and analysis of the effluent water from the column
test were also studied to better understand the species removed by
the LDH. These results show that the LDH is a promising sorbent for
removing selenium from wastewaters with high levels of sulfate and
background species.