Study of the Cationic Photopolymerization of Multifunctional Propenyl Ether Monomers

Crivello, James V.; Bratslavsky, S. A.

doi:10.1080/10601329409350108

Cited by 16 publications

(2 citation statements)

References 12 publications

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“…Superacids can catalyze the homo-polymerization and co-polymerization of epoxies with hydroxyl functional polymers, cyclic ester, oxetane [20], and vinylether reactants. Most of the cationic catalysts are activated by UV radiation [21]. Recently, quaternary ammonium blocked hexafluoroantimonate and triflic acid catalysts [22] have been introduced for thermal cationic cure.…”

Section: Amino Formaldehyde Resinsmentioning

confidence: 99%

Advances in Catalysis for Organic Coatings

Blank¹

2002

Chimia

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The industrial coating market is undergoing substantial changes. These changes are driven predominately by environmental regulations. The reduction in organic solvent content and the elimination of certain heavy metals and toxic compounds in industrial coatings are major priorities. The development of powder, waterborne, high solids or solvent-free coatings also requires catalyst systems with different reaction profiles.

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Section: Amino Formaldehyde Resinsmentioning

confidence: 99%

Advances in Catalysis for Organic Coatings

Blank¹

2002

Chimia

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“…6). 7,10 Similarly, the isomerization of 2-vinyl-1,3-dioxolanes to ketene acetals in high yields has also been achieved using this versatile catalyst.…”

Section: Introductionmentioning

confidence: 96%

Synthesis and cationic photopolymerization of 1-butenyl and 1-pentenyl ethers

Kaur

Crivello

Pascuzzi

1999

J. Polym. Sci. A Polym. Chem.

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Synthesis and cationic photopolymerization of monomers based on nopol

Crivello

Liu

1999

J. Polym. Sci. A Polym. Chem.

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Starting with nopol [(R)‐(−)‐2‐(2′‐hydroxyethyl)‐6,6‐dimethyl‐8‐oxatricyclo[3.1.1.12,3]octane, I] as a substrate, two new, interesting monomers, allyl nopol ether epoxide III and nopol 1‐propenyl ether epoxide IV, were prepared. The photoinitiated cationic polymerizations of these two monomers as well as several other model compounds were studied using real‐time infrared spectroscopy. Surprisingly, the rates of epoxide ring‐opening polymerization of both monomers were enhanced as compared to those of the model compounds. Two different mechanisms which involve the free radical induced decomposition of the diaryliodonium salt photoinitiator were proposed to explain the rate acceleration effects. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 1199–1209, 1999

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Study of the Cationic Photopolymerization of Multifunctional Propenyl Ether Monomers

Cited by 16 publications

References 12 publications

Advances in Catalysis for Organic Coatings

Advances in Catalysis for Organic Coatings

Synthesis and cationic photopolymerization of 1-butenyl and 1-pentenyl ethers

Synthesis and cationic photopolymerization of monomers based on nopol

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