Study of the Critical Pore Radius That Results in Critical Gas Saturation during Methane Hydrate Dissociation at the Single-Pore Scale: Analytical Solutions for Small Pores and Potential Implications to Methane Production from Geological Media

Abstract

We examine the critical pore radius that results in critical gas saturation during pure methane hydrate dissociation within geologic porous media. Critical gas saturation is defined as the fraction of gas volume inside a pore system when the methane gas phase spans the system. Analytical solutions for the critical pore radii are obtained for two, simple pore systems consisting of either a single pore-body or a single pore-body connected with a number of pore-throats. Further, we obtain critical values for pore sizes above which the production of methane gas is possible. Results shown in the current study correspond to the case when the depression of the dissociation temperature (due to the presence of small-sized pores; namely, with a pore radius of less than 100 nm) is considered. The temperature shift due to confinement in porous media is estimated through the well-known Gibbs-Thompson equation. The particular results are of interest to geological media and particularly in the methane production from the dissociation of natural hydrate deposits within off-shore oceanic or on-shore permafrost locations. It is found that the contribution of the depression of the dissociation temperature on the calculated values of the critical pore sizes for gas production is limited to less than 10% when compared to our earlier study where the porous media effects have been ignored.

Affecting Mechanism of Natural Sandstone Porous Media on the Formation and Phase Equilibrium of Methane Hydrate

“…The results showed that, in comparison to the phase equilibrium in pure water, ZnO presented a slight thermodynamic inhibitory effect on the formation of hydrates. Tsimpanogiannis et al 31 adopted various porous media materials with different pore structures to study the critical pore diameter that could lead to critical gas saturation during the decomposition process of methane hydrates. They found that the decomposition temperature had a relatively small effect on the critical pore diameter for gas production and that the porous media might have a related impact.…”

Evaluation of a Simplified Model for Three-Phase Equilibrium Calculations of Mixed Gas Hydrates

“…The recoverable amount of methane is, however, an issue that is currently under debate [16][17][18]. Methane production from the dissociation of hydrates confined within marine sediments requires a better understanding of the interactions between the dissociation thermodynamics occurring under different types of confinement, hydrate saturations, and the different production schemes (i.e., depressurization, thermal stimulation, hydrate inhibitor injection) [19][20][21][22][23]. Significant challenges need to be addressed in an adequate manner in order to incorporate hydrate deposits into the future energy mix in use [7,24].…”