The application of
polymer-based relative permeability modifiers
(RPM) in low-permeability sandstone reservoirs has long intrigued
production engineers. We hypothesize that lowering salinity may expand
the application of the cationic polyacrylamide (CPAM) in low-permeability
sandstone gas reservoirs, because of the favorable polymer–polymer
physiochemical interaction at pore surfaces. To test this hypothesis,
we conducted six core-flooding experiments to examine the relative
permeabilities of water/gas before and after CPAM treatment, as a
function of salinity using sandstone core plugs. Moreover, we measured
zeta potentials of polymer–polymer, rock–polymer, and
rock–brine interfaces before and after the RPM treatment, as
a function of salinity. We also measured the contact angles for silicate/brine
systems before and after the treatment as a function of salinity.
Core-flooding results show that reducing the salinity decreases the
water relative permeability but with marginal effect on the gas relative
permeability. Lowering salinity also decreases the effective polymer
layer thickness at pore surfaces. Moreover, the adsorption of the
CPAM onto the negatively charged sandstone rock, together with lowering
brine salinity, increases hydrophobicity of the rock. Thus, our results
suggest that polymer–polymer interactions at pore surfaces
govern the performance of CPAM in low-permeability sandstone rocks.