“…Consequently, the nanoscopic strain in the disordered fraction would increase from cycle to cycle, whereas the probed ε n would decrease slightly, as is observed in the experiments. In the literature similar softening effects of compatibilizers on the matrix of nanocomposites have been reported [43,44] and sideeffects of additive migration in blends and composites have been studied [45][46][47] . By the way, migration of compatibilizer into the polyamide cannot be studied by means of SAXS data from the studied materials.…”
Section: Response Of Stress and Nanoscopic Strainmentioning
confidence: 80%
“…This result indicates the complexity of composite design, because the desired effects of an additive or a processing step may be accompanied by side effects [43][44][45][46][47] .…”
Oriented precursors of MFCs consisting of HDPE and PA6 or PA12 are studied during strain‐controlled slow load‐cycling. In the PA6‐containing blends a strongly retarded nanostrain response is detected. Compatibilization induces nanostrain heterogenization. Stress fatigue is lower in the PA12 blends, but hardly decreased by the compatibilizer. Selective migration of the compatibilizer into a disordered semi‐crystalline fraction of the HDPE matrix can explain the findings. The semi‐crystalline HDPE entities in PA6 blends appear more disordered than in PA12‐blends. An analysis of the HDPE nanostructure evolution during cycling reveals epitaxial strain crystallization. Uncompatibilized PA6 blends cycled about high pre‐strain show plastic flow but nanoscopic shrinkage in the semi‐crystalline stacks. magnified image
“…Consequently, the nanoscopic strain in the disordered fraction would increase from cycle to cycle, whereas the probed ε n would decrease slightly, as is observed in the experiments. In the literature similar softening effects of compatibilizers on the matrix of nanocomposites have been reported [43,44] and sideeffects of additive migration in blends and composites have been studied [45][46][47] . By the way, migration of compatibilizer into the polyamide cannot be studied by means of SAXS data from the studied materials.…”
Section: Response Of Stress and Nanoscopic Strainmentioning
confidence: 80%
“…This result indicates the complexity of composite design, because the desired effects of an additive or a processing step may be accompanied by side effects [43][44][45][46][47] .…”
Oriented precursors of MFCs consisting of HDPE and PA6 or PA12 are studied during strain‐controlled slow load‐cycling. In the PA6‐containing blends a strongly retarded nanostrain response is detected. Compatibilization induces nanostrain heterogenization. Stress fatigue is lower in the PA12 blends, but hardly decreased by the compatibilizer. Selective migration of the compatibilizer into a disordered semi‐crystalline fraction of the HDPE matrix can explain the findings. The semi‐crystalline HDPE entities in PA6 blends appear more disordered than in PA12‐blends. An analysis of the HDPE nanostructure evolution during cycling reveals epitaxial strain crystallization. Uncompatibilized PA6 blends cycled about high pre‐strain show plastic flow but nanoscopic shrinkage in the semi‐crystalline stacks. magnified image
“…The interfacial mass transport to the surrounding medium has been found to be the limiting step rather than diffusion of the plasticizer through the matrix to the surface. This rate is usually a function of temperature and initial plasticizer concentration (Foldes, 1998). If plasticizers leach out to a liquid, polymers fail to retain their flexibility while the loss of plasticizers leaves the polymers inappropriate for the desired application.…”
Section: Plasticizer Leaching Out Of Polymer and Methods Of Reductionmentioning
“…[17] Photostability of HDPE film containing surface treated phthalocyanine pigment If the assumption described above is valid, a coating of the pigment particles with a layer hindering the interaction with the stabiliser molecules should improve the stability. For this purpose a layer of reactive surfactant (RS) [11] was applied.…”
Section: Characteristics and Chemical Processesmentioning
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