1992
DOI: 10.1007/bf02636342
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Study of the polymorphism and the crystallization kinetics of tripalmitin: A microscopic approach

Abstract: The morphology and kinetics of crystallization of tripalmitin have been examined in detail by optical microeco W. The a-crystallization process is characterized by a fast heterogeneous nucleation and spherulitic growth, even at low undercooling, resulting in intense birefrlngence and smooth spheruiitie entities. Four different fJ'-microstructures have been found--grainy, fibrous, feathery and lamellar. Around 47°C, a clear change from a grainy to a fibrous/3'-microstructure is observed. This transition seems t… Show more

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Cited by 106 publications
(74 citation statements)
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“…Above this value, as the results observed in this work after 90 minutes of crystallization, the granular structure is indicative of the presence of b' polymorph, for the samples Blend A, Blend B, Blend C, Braz A and Braz B. The simultaneous presence of larger disks and spherulites (close to 50 mm) for Braz C evidences, therefore, a possible polymorphic b' → b transition, confirming a distinct crystallization pattern for this sample (Rousseau, 2007;Kellens et al, 1992). This behavior may be related to the development of crystals with undesirable dimensions hence weaker crystalline networks, which causes a decay in consistency and loss of gloss in chocolate-based products (Timms, 2003).…”
Section: Microstructuresupporting
confidence: 83%
“…Above this value, as the results observed in this work after 90 minutes of crystallization, the granular structure is indicative of the presence of b' polymorph, for the samples Blend A, Blend B, Blend C, Braz A and Braz B. The simultaneous presence of larger disks and spherulites (close to 50 mm) for Braz C evidences, therefore, a possible polymorphic b' → b transition, confirming a distinct crystallization pattern for this sample (Rousseau, 2007;Kellens et al, 1992). This behavior may be related to the development of crystals with undesirable dimensions hence weaker crystalline networks, which causes a decay in consistency and loss of gloss in chocolate-based products (Timms, 2003).…”
Section: Microstructuresupporting
confidence: 83%
“…The polymorphic and phase behavior as well as the crystallization kinetics of pure tripalmitin and tristearin has been reported previously in the literature (6)(7)(8)(9)(10). However, relatively few studies have been performed on blends of tripalmitin and tristearin, although a phase diagram is well established (11)(12)(13).…”
mentioning
confidence: 90%
“…It is worthy of note that various morphologies of β -form PPP crystals have been found for different temperature treatments. In particular, the β -form showed needle-like crystals after slow crystallisation, similar to β-form crystals, which usually exhibit a long needle shape (Kellens et al, 1992).…”
Section: Polymorphic Transformation Of Fatsmentioning
confidence: 99%