In the present study, PS@a-Fe 2 O 3 nanocomposites were prepared by chemical microemulsion polymerization approach and the ability of magnetic beads to remove Cu(II) ions from aqueous solutions in a batch media was investigated. Various physico-chemical parameters such as pH, initial metal ion concentration, temperature, and equilibrium contact time were also studied. Adsorption mechanism of Cu 21 ions onto magnetic polymeric adsorbents has been investigated using Langmuir, Freundlich, Sips and Redlich-Petersen isotherms. The results demonstrated that the PS@a-Fe 2 O 3 nanocomposite is an effective adsorbent for Cu 21 ions removal. The Sips adsorption isotherm model (R 2 > 0.99) was more in consistence with the adsorption isotherm data of Cu(II) ions compared to other models and the maximum adsorbed amount of copper was 34.25 mg/g. The adsorption kinetics well fitted to a pseudo second-order kinetic model. The thermodynamic parameters (DH8, DS8, and DG8) were calculated from the temperature dependent sorption isotherms, and the results suggested that copper adsorption was a spontaneous and exothermic process.