The microscale/nanoscale lamellar-structure WS 2 particles with sizes of 2 µm and 500 nm were synthesized by solid-phase reaction method and characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The synergies between microscale/nanoscale WS 2 particles and ZDDP as lubricating oil additives was evaluated by means of UMT-2 tribometer at room temperature. The wear scars were examined with SEM and electron-probe micro-analyzer (EPMA). The results show that the anti-wear properties were improved and the friction coefficient was greatly decreased with the simultaneous addition of WS 2 particles and ZDDP, and the largest reduction of friction coefficient was 47.2% compared with that in base oil. Moreover, the presence of ZDDP additive in the lubricant further enhances the friction-reduction and anti-wear effect of microscale/nanoscale WS 2 . This confirms that there is a synergistic effect between WS 2 particles and ZDDP.