“…12 However, there is a large residual stress in the C/C-metals brazed joints due to the large coefficient of thermal expansion (CTE) mismatches between C/C composites and metals, which will damage the mechanical properties of joints and even directly lead to joint failure. 13,14 In order to relieve the residual stress in the joints of heterogeneous materials, composite brazing by introducing reinforcements with low CTE and high-temperature resistance into the joining layer was developed. 15 In the reported composite brazing, there are mainly two methods to introduce reinforcements into the joining layer: one is to directly add the reinforcements, such as SiC particles, 16 Carbon, Nano-Al 2 O 3 , 17 and W particles, 18 into the powder fillers before brazing; the other is to synthesize reinforcements, such as TiB, 19 TiC 20 and AgTi compounds, 21 through in-situ reactions between powder fillers during brazing.…”