Study on application of membrane reactor in direct synthesis DMC from CO2 and CH3OH over Cu–KF/MgSiO catalyst

Research Progress in the Direct Synthesis of Dimethyl Carbonate from CO2 and Methanol

“…Membrane catalytic reactor (MCR) combining catalytic reaction with membrane separating process has been studied by Li et al [66]. for the synthesis of DMC.…”

Synthesis of Linear and Cyclic Carbonates

“…The data collected data also permit simulations to be prepared of the separation steps of the outlet feed, in order to optimize the integrated process reactionseparation. The membrane technology for DMC separation has also been investigated very recently [83] , whilst chemical engineering -and, in particular, reactor design -being considered of equal importance to the chemistry of the process if the thermodynamic equilibrium is to be shifted favorably, as can be achieved with a membrane catalytic reactor [84] . The enthalpy and free energy calculations of the reaction from methanol (Equation 7.8 ) show that the reaction is slightly exothermic, but does not occur spontaneously due to ∆ G > 0.…”

Formation of magnesium silicate on surface of silica for steam reforming of liquefied petroleum gas

“…Recently, magnesium silicate and its derivatives due to their tunable properties have been attracted a considerable amount of researches for advanced applications as catalyst or catalyst support [14][15][16][17][18][19][20]. Magnesium silicate materials were usually synthesized above 1000°C, leading to low surface area and small porosity, which limit their catalytic applications.…”