2021
DOI: 10.1016/j.ceramint.2021.07.117
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Study on cyclic thermal corrosion behavior of APS-7YSZ thermal barrier coating at room- and high temperature

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Cited by 16 publications
(4 citation statements)
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“…Al element is insufficient to form a continuously dense Al 2 O 3 barrier layer, and Ni, Cr, and Co diffuse outward through the broken Al 2 O 3 and further react with O 2 . The chemical reaction sequence is as follows Equations () 22–24 (according to ∆ r G m – T diagram): Al 2 O 3 → Cr 2 O 3 → CoO → NiO, and gray (Ni, Co)Cr 2 O 4 is generated in the later stage of oxidation. Literature reported that (Ni, Co)Cr 2 O 4 has high brittleness and less adhesive ability, causing high growth stresses in the TGO layer, 24,25 which degrades the stress tolerance and physical properties of the YSZ layer and eventually leads to severe fracture failure during high‐temperature air exposure (see Figure 11 C1).…”
Section: Resultsmentioning
confidence: 99%
“…Al element is insufficient to form a continuously dense Al 2 O 3 barrier layer, and Ni, Cr, and Co diffuse outward through the broken Al 2 O 3 and further react with O 2 . The chemical reaction sequence is as follows Equations () 22–24 (according to ∆ r G m – T diagram): Al 2 O 3 → Cr 2 O 3 → CoO → NiO, and gray (Ni, Co)Cr 2 O 4 is generated in the later stage of oxidation. Literature reported that (Ni, Co)Cr 2 O 4 has high brittleness and less adhesive ability, causing high growth stresses in the TGO layer, 24,25 which degrades the stress tolerance and physical properties of the YSZ layer and eventually leads to severe fracture failure during high‐temperature air exposure (see Figure 11 C1).…”
Section: Resultsmentioning
confidence: 99%
“…These molten salts can penetrate the coating at high temperatures and react with the stabilizers in the coating. The phase changes during the reaction can lead to concentrated thermal stresses within the coating, triggering premature coating failure [17]. Therefore, modifying YSZ with rare earth oxides such as La 2 O 3 , Sc 2 O 3 , Gd 2 O 3 , Yb 2 O 3 , and CeO 2 has become a focal point of current research [18][19][20][21][22][23].…”
Section: Introductionmentioning
confidence: 99%
“…4 The most commonly used TC material is yttriastabilized zirconia (YSZ), which is characterized by low thermal conductivity, good phase stability, and high thermal expansion coefficient. [5][6][7] The common BC material is MCrAlY (M: Ni, Co, and Ni + Co), which is necessary to accommodate the thermal expansion misfit between the ceramic coating and the substrate. 8,9 During hightemperature service, there will be a thermally grown oxide (TGO) layer formed between the TC layer and the BC layer, which consists of mixed oxide clusters of chromium (Cr, Al) 2 O 3 , spinel Ni(Cr, Al) 2 O 4 , and nickel oxide NiO (CSN).…”
Section: Introductionmentioning
confidence: 99%
“…The representative TBCs are composed of top coating (TC) and bond coating (BC) applied on the substrate 4 . The most commonly used TC material is yttria‐stabilized zirconia (YSZ), which is characterized by low thermal conductivity, good phase stability, and high thermal expansion coefficient 5–7 . The common BC material is MCrAlY (M: Ni, Co, and Ni + Co), which is necessary to accommodate the thermal expansion misfit between the ceramic coating and the substrate 8,9 .…”
Section: Introductionmentioning
confidence: 99%