Study on the constitutive model of NEPE propellant based on indentation creep

Abstract

The significance of the mechanical properties of solid propellant during the curing process lies in their contribution to stress‐strain calculations of viscoelastic engineering materials and the analysis of structural integrity of solid rocket motor charges. In order to study the Constitutive equation of the nitrate ester plasticized polyether (NEPE) propellant during the curing process, indentation creep tests were carried out on the NEPE propellant, and the viscoelastic constitutive model of propellant with curing reaction at 50 °C and atmospheric pressure was studied. Firstly, based on the viscoelastic theory, the experimental principle of indentation creep test is deduced, and indentation creep tests are carried out for propellants with different curing degrees. Then, based on 2S2P1D (2 Springs, 2 Parabolic elements, 1 Dashpot) model and time‐temperature equivalence principle, the indentation test data are processed, and the complex modulus master curve of propellant with different curing degrees is established, and the influence of curing reaction on viscoelastic properties of propellant is analyzed, so as to better understand the response characteristics of propellant system during curing. The results show that the 2S2P1D model has a good fitting effect for the master curve in low frequency period, the fitting error is controlled within 10 %, and the correlation coefficients are all above 0.95. With the curing reaction, the complex modulus gradually increases, while the change rate gradually decreases. And it tends to be stable on the seventh day.