Titanium aluminide (TiAl) alloys have emerged as promising materials for high-temperature applications due to their unique combination of high-temperature strength, low density, and excellent oxidation resistance. However, the fabrication of TiAl alloys using conventional methods is challenging due to their high melting points and limited ductility. Selective laser melting (SLM), an additive manufacturing technique, offers a viable solution for producing TiAl alloys with intricate geometries and the potential for tailoring their microstructure. This study investigates the effect of in situ copper alloying and multiple laser scans on the microstructure and mechanical properties of TiAl-based alloys fabricated using SLM. The results demonstrate that copper alloying enhances the formation of the α2-Ti3Al phase, refines the microstructure, and improves the mechanical properties of TiAl alloys. Multiple laser scans allow for the creation of distinct microstructural regions within a single component, enabling the tailoring of properties that are suitable for specific operating conditions. The findings provide valuable insights into the fabrication and optimization of TiAl intermetallic alloys with diverse applications.