“…Nowadays, the widespread use of chemical fuels has caused the atmospheric concentration of carbon dioxide (CO 2 ) to rise quickly, causing global warming issues. − Therefore, the conversion of CO 2 into useful carbon-based products is urgently needed, which is important for realizing a carbon-neutral cycle. , In recent years, the electrochemical CO 2 reduction reaction (CO 2 RR) has caught the eye of widespread researchers . The CO 2 RR could deplete CO 2 while producing high-added-value carbon products, such as CO, CH 4 , HCOOH and CH 3 OH. , However, CO 2 RR usually exhibits poor catalytic selectivity and low energy conversion efficiency because of the strong CO bond, the low electron affinity, and the competitive hydrogen evolution reaction (HER). , Carbon monoxide (CO), as a CO 2 RR product, is an important chemical feedstock for some synthetic reactions, such as Fischer–Tropsch synthesis and oxalic acid synthesis .…”