This investigation evaluates the effectiveness of UV-365 nm/S 2 O 8 2-process in degrading polyvinyl alcohol in aqueous solutions. The effects of pH, Na 2 S 2 O 8 dosage, and temperature on the degradation efficiency of polyvinyl alcohol were studied. Under acidic conditions, the degradation efficiency of polyvinyl alcohol exceeded that under alkaline conditions. Additionally, a higher Na 2 S 2 O 8 dosage and a higher temperature were associated with a higher degradation efficiency of polyvinyl alcohol. The degradation rates of polyvinyl alcohol followed a pseudo-first-order kinetic model. Moreover, the observed degradation rate coefficient increased from 0.0078 to 0.4081 min -1 when the temperature was increased from 10 to 55°C. Also, the activation energy estimated using the observed degradation rate coefficients and the Arrhenius equation was 64 kJ/mol. At UV-365 nm, pH 3, an Na 2 S 2 O 8 dosage of 0.06 g/L, a temperature of 55°C, and an initial polyvinyl alcohol concentration of 20 mg/L, around 100 % of polyvinyl alcohol was degraded, indicating that UV-365 nm/S 2 O 8 2-process has great potential in degrading polyvinyl alcohol in aqueous solutions.