Sub-micron sized saccharide fibres via electrospinning

Abstract

Abstract:In this work, the production of continuous submicron diameter saccharide fibres is shown to be possible using the electrospinning process. The mechanism for the formation of electrospun polymer fibres is usually attributed to the physical entanglement of long molecular chains. The ability to electrospin continuous fibre from a low molecular weight saccharides was an unexpected phenomenon. The formation of sub-micron diameter "sugar syrup" fibres was observed in situ using highspeed video. The trajectory of the electrospun saccharide fibre was observed to follow that typical of electrospun polymers. Based on initial food grade glucose syrup tests, various solutions based on combinations of syrup components, i.e. mono-, di-and tri-saccharides, were investigated to map out materials and electrospinning conditions that would lead to the formation of fibre. This work demonstrated that sucrose exhibits the highest propensity for fibre formation during electrospinning amongst the various types of saccharide solutions studied. The possibility of electrospinning low molecular weight saccharides into sub-micron fibres has implications for the electrospinability of supramolecular polymers and other biomaterials.

Nanoliflerin Ayçiçeği (Helianthus annuus) Yağına Eklenmesinin Yağın Viskozitesi Üzerine Etkisi

“…A preliminary electrospinning trial was carried out to produce electrospin fibre mats from PVOH and zein. The production of zein nanofibres by electrospinning has been widely reported elsewhere [2,8], and glacial acetic acid was confirmed to give better spinning continuity than aqueous ethanol [10]. This choice of polymer and solvent system gave a range of fibre sizes, so that the effect of change in surface to volume ratio could be examined.…”