2024
DOI: 10.1039/d3nh00358b
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Sublimation-based wafer-scale monolayer WS2 formation via self-limited thinning of few-layer WS2

Mingxi Chen,
Jianwei Chai,
Jing Wu
et al.

Abstract: Atomically-thin monolayer WS2 is a promising channel material for next-generation Moore’s nanoelectronics owing to its high theoretical room temperature electron mobility and immunity to short channel effect. The high photoluminescence...

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Cited by 6 publications
(3 citation statements)
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“…Such high operating temperatures not only lead to increased power consumption but also pose safety concerns in potentially explosive gas environments. In this regard, achieving room-temperature detection of NO 2 is a challenging issue that must be addressed. Tungsten disulfide (WS 2 ) nanosheets (NSs), as one of the typical two-dimensional (2D) transition metal dichalcogenides (TMDs), have become ideal candidates for room-temperature gas sensors due to their large surface areas and high carrier mobilities at room temperature. In addition, WS 2 NSs can be obtained via diverse preparation methods with excellent scalability, leading to wide applications in the fields of flexible and wearable devices. The 2D structure of the WS 2 nanosheets offers a considerably expanded surface area, which facilitates a greater number of adsorption sites for gas molecules. However, the desorption of these adsorbed gas molecules becomes challenging due to the insufficient activation energy at room temperature.…”
Section: Introductionmentioning
confidence: 99%
“…Such high operating temperatures not only lead to increased power consumption but also pose safety concerns in potentially explosive gas environments. In this regard, achieving room-temperature detection of NO 2 is a challenging issue that must be addressed. Tungsten disulfide (WS 2 ) nanosheets (NSs), as one of the typical two-dimensional (2D) transition metal dichalcogenides (TMDs), have become ideal candidates for room-temperature gas sensors due to their large surface areas and high carrier mobilities at room temperature. In addition, WS 2 NSs can be obtained via diverse preparation methods with excellent scalability, leading to wide applications in the fields of flexible and wearable devices. The 2D structure of the WS 2 nanosheets offers a considerably expanded surface area, which facilitates a greater number of adsorption sites for gas molecules. However, the desorption of these adsorbed gas molecules becomes challenging due to the insufficient activation energy at room temperature.…”
Section: Introductionmentioning
confidence: 99%
“…Garoli et al [26] used FIB to successfully prepare nanopores with a pore size of less than 10 nm on MoS 2 membranes and achieved high pAttern repeatability to prepare multi-point nanopores. Monolayer WS 2 has the same thickness as MoS 2 [27], but its photoluminescence (PL) quantum yield is higher than that of MoS 2 , which makes the application of WS 2 in optoelectronic devices possible [28]. Danda et al [22] used TEM electron beams to drill nanopores with a sub-5 nm aperture on WS 2 monolayers characterised by the PL spectrum and successfully identified various pore postures of double-stranded DNA.…”
Section: Introductionmentioning
confidence: 99%
“…1–6 TMDCs, with the general formula MX 2 (where M represents transition metals like Mo, W, Sn, Nb, Zr, and X denotes chalcogens such as S, Se, and Te), can be easily exfoliated into monolayers or few-layers, enabling bandgap tuning and utilization in various photosensitive devices. 7–10 While MoS 2 and WS 2 have been extensively studied and are more accessible, their limited abundance on Earth and complex synthesis processes raise costs, hindering their industrial-scale application in optoelectronics. To address these challenges, Tin dichalcogenide (SnS 2 ) emerges as a promising alternative due to its abundant and eco-friendly nature, coupled with excellent absorption coefficients in the UV-visible region and rapid diffusion rates of electron–hole pairs, showing immense potential in diverse photosensitive devices.…”
Section: Introductionmentioning
confidence: 99%