2006
DOI: 10.1016/j.jct.2005.12.012
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Sublimation study of anhydrous ferric chloride

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Cited by 9 publications
(12 citation statements)
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“… a The atomic data of ref were used for the calculation. Crystal formation enthalpy (FeF 3 : −1041.8 and) and entropies (FeF 3 : 98.3 and FeCl 3 : 142.2 J/mol.K) are from ref , and formation enthalpy of FeCl 3 (−396.0 kJ/mol) is from ref . b Ref . …”
Section: Discussionmentioning
confidence: 99%
See 1 more Smart Citation
“… a The atomic data of ref were used for the calculation. Crystal formation enthalpy (FeF 3 : −1041.8 and) and entropies (FeF 3 : 98.3 and FeCl 3 : 142.2 J/mol.K) are from ref , and formation enthalpy of FeCl 3 (−396.0 kJ/mol) is from ref . b Ref . …”
Section: Discussionmentioning
confidence: 99%
“…The enthalpy of sublimation can be calculated as the difference of the enthalpies of formation of the gas-phase iron trichloride dimer and the iron trichloride crystal, these are also given in Table . While the enthalpy of sublimation for the monomer FeCl 3 , 146.4 kJ/mol, is only slightly higher than that for the dimer, 141.7 kJ/mol, the free energies of sublimation (FeCl 3 : 85.9 and Fe 2 Cl 6 : 68.9 kJ/mol) already suggest larger vapor pressure for the dimer, indicating that this is mostly an entropy effect.…”
Section: Discussionmentioning
confidence: 99%
“…As the saturated vapor pressure of FeCl3 at 20 °C is very low [46], the excess FeCl3; i.e., not participating in the formation of PEDOT, could condensate on the film during its deposition and partly decompose into sub-chlorides which, in turn, could be hydrolyzed to iron hydroxides upon exposure to air. These results indicate that the investigated FeCl3/EDOT ratios are systematically larger than the optimum one resulting in films with the highest electrical conductivity and lowest impurities.…”
Section: Fecl3/edot Ratiomentioning
confidence: 99%
“…24 According to the previous research report on the sublimation of FeCl 3 (s) in the range of 150−300 °C, the dominant species in the vapor are FeCl 3 (g) and Fe 2 Cl 6 (g) in equilibrium with FeCl 3 (s). 25 pressure of the FeCl 3 (g)/Fe 2 Cl 6 (g) is small in the temperature range of 150−300 °C, the derived vapor is enough to be used as catalyst for oxidative coupling reaction due to the full contact of the catalytic vapor and monomers. 26 Up to now, catalytic vapor is nearly disregarded for preparation of POPs.…”
Section: ■ Introductionmentioning
confidence: 99%