Zeolite is used for the decontamination of radioactive water, which contains salts from seawater, accumulated in the Fukushima Daiichi Nuclear Power Plant. The evaluation of hydrogen production by water radiolysis during the decontamination process is important for safe operation. Thus, hydrogen production from a mixture of zeolite and seawater was studied by a γ-radiolysis experiment, and the hydrogen production during the process was evaluated. The measured yield of hydrogen from seawater was comparable to the primary yield in the γ-radiolysis of water. This result indicates that the oxidation of hydrogen by the radical products of water radiolysis is not effective in seawater. The measured yield from the mixture decreased at a high weight fraction of zeolite. However, the measured yield was higher than that expected from the direct radiolysis of water in the mixture, which would decrease proportionally to the weight fraction of water. This result suggests that the radiation energy deposited on the zeolite is involved in hydrogen production. From the measured yields, the hydrogen production rate was evaluated to be 3.6 mL/h per t of radioactive water before the process and 1.5 L/h per t of waste adsorbent after the process.