Microplastics
of size <25 μm possess globally transportable
features, but the impact of precipitation on their transport remains
unclear. Here, microplastics were detected in all 10 studied rainfalls
in Beijing, with <25 μm microplastics present in 8 rainfalls.
Interestingly, microplastic abundance (7590–136,778 items·m–3) was tentatively linked to maximum rainfall intensity,
with <25 μm microplastics making up 39.6 (±27.5)% of
the total count. The composition of <25 μm microplastics
differed from that of larger microplastics, although both mainly comprised
polystyrene, polyethylene, and polypropylene. The microplastic communities
differed among rainfalls, suggesting that atmospheric transport is
a highly dynamic process. The first rainfall exhibited the highest
microplastic abundance and community diversity after long-term exposure
to dry atmospheric environment. The deposited microplastics were unstable
and highly fragmented according to the conditional fragmentation model.
The wet deposition rate of the microplastics was calculated as 2–463
μg·m–2 (146–8629 items·m–2) per rain, amounting to 25.44 tons per annum in Beijing.
Although <25 μm microplastics represented a negligible proportion
(0.00–1.24%) of the overall mass load of microplastics, their
numerical abundance was high. Our results demonstrate that precipitation
is an effective mechanism for removing airborne microplastics, which
may enter urban soils and waters, exacerbate microplastic burdens
in the environment, and cause potential risk for human health.