2005
DOI: 10.1107/s0108768105008797
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Substituent effects in bis(arene)chromium compounds containing a CN group in the aromatic ring

Abstract: The crystal structures of Cr(PhCN)(2) (2), (PhCN)Cr(PhCH(3)) (3) and (PhCN)Cr(PhCF(3)) (4) prepared by means of the Metal Vapor Synthesis (MVS) technique have been determined. Compounds (2), (3) and (4) crystallize as discrete sandwich complexes having intrinsic C(2v)(mm2), C(s)(m) and C(1)(1) symmetries, respectively. The X-ray diffraction study has revealed a synperiplanar conformation for (2) and (3), and a synclinal conformation for (4) with a torsion angle (C(ipso)1-Centroid1-Centroid2-C(ipso)2) of phi = … Show more

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Cited by 4 publications
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“…For their mutagenic and carcinogenic properties, see Debnath et al (1991). For previous studies showing distortions induced in aromatic rings, see Murray-Rust (1982), Allen et al (1998), and Khrustalev et al (2005). For the preparation, see: Goossen et al (2007).…”
Section: Related Literaturementioning
confidence: 99%
“…For their mutagenic and carcinogenic properties, see Debnath et al (1991). For previous studies showing distortions induced in aromatic rings, see Murray-Rust (1982), Allen et al (1998), and Khrustalev et al (2005). For the preparation, see: Goossen et al (2007).…”
Section: Related Literaturementioning
confidence: 99%