Substitution-induced nitrogen-nitrogen coupling for nitride coordinated to osmium(VI)

Ware, David C.; Taube, Henry

doi:10.1021/ic00024a029

Cited by 98 publications

(76 citation statements)

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“…Such terminal phosphide dimerization with P-P bond formation and reduction of the metal oxidation state is reminiscent of similar dimerization pathways that have been observed for group 8 metal nitrido systems, leading to bridging dinitrogen complexes. [80][81][82] The concept of using ligand susbstitution in a post-P 4 activation step to open up new synthetic access to phosphide systems deserves more exploration.…”

Section: Methodsmentioning

confidence: 99%

Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

2010

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Introduction 4164 2. P 4 Activation Leading to P 1 , P 2 , and P 3 Products 4165 2.1. Terminal and Bridging P 1 Ligands from P 4 4165 2.2. Bridging P 2 Ligands from P 4 4166 2.3. Cyclo-P 3 Units Derived from P 4 4168 3. P 4 Activation Leading to P 4 Products 4169 3.1. Coordination of P 4 Tetrahedra 4169 3.2. Rearranged P 4 Products 4169 4. P 4 Activation Leading to P g5 Products 4171 5. Functionalization and Transfer Methodologies 4173 5.1. Functionalization and Subsequent Reactivity of Terminal Monophosphide and Bridging Diphosphorus Complexes Derived from P 4 4173 5.2. Reactivity and Transfer Chemistry of the Cyclo-P 3 Functional Group 4174 5.3. Functionalization and Transfer Chemistry of Polyphosphorus Ligands (P g4 ) Derived from P 4 4175 6. Concluding Remarks 4175 6.1. Conclusions 4175 6.2. Future Prospects 4176 7. Acknowledgments 4176 8. References 4176

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Section: Methodsmentioning

confidence: 99%

Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

2010

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“…A broad range of ligands have been used to support Os(VI) nitrido species. These may be generally classified as halogen and pseudohalogen ligands, [51][52][53][54][55][56][57][58][59][60] amines, [62,63] alkoxides, [64,65] polypyridyl ligands, [66][67][68][69][70][71][72] and polyoxometallates. [73][74][75][76] Organometallic Os(VI) nitrido species are also known.…”

Section: Imido Complexes Of the Late Transition Metals 37mentioning

confidence: 99%

Terminal Nitrido and Imido Complexes of the Late Transition Metals

Berry

2009

Comments on Inorganic Chemistry

285

232

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Compounds that contain a late transition metal-nitrogen multiple bond represent important reactive intermediate species in many useful organic and inorganic transformations. In order to understand the role that these intermediates play in reactions, it is important to have a full understanding of their electronic structure. This paper reviews the known structural motifs that occur in late transition metal nitrido and imido compounds, and provides a correlation between geometric structure and electronic structure. Also, intermediate species that have been postulated but not yet isolated are discussed, as these compounds represent exciting targets for further efforts in synthetic inorganic chemistry.

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“…Last but not least, the oxidation product [Os VI (NH 3 ) 4 N] 3+ must be reduced in order to regenerate the starting complex [Os II (NH 3 ) 5 (N 2 )] 2+ . Some previous studies indicate that such a reduction may be achieved thermally [14] or photochemically [5,6,15]. For the conversion and chemical storage of solar energy reaction 2 and the reduction of the Os(VI) complex have to be incorporated into a cyclic system which then proceeds photocatalytically.…”

Section: Discussionmentioning

confidence: 99%

Photolysis of Aqueous [Os(NH₃)₅(N₂)]²⁺. Photoreduction of Coordinated Dinitrogen to Hydrazine as a Model for a New Type of Artificial Photosynthesis?

Kunkely

Vogler

2012

Zeitschrift Für Naturforschung B

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Substitution-induced nitrogen-nitrogen coupling for nitride coordinated to osmium(VI)

Cited by 98 publications

References 1 publication

Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

Terminal Nitrido and Imido Complexes of the Late Transition Metals

Photolysis of Aqueous [Os(NH₃)₅(N₂)]²⁺. Photoreduction of Coordinated Dinitrogen to Hydrazine as a Model for a New Type of Artificial Photosynthesis?

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Substitution-induced nitrogen-nitrogen coupling for nitride coordinated to osmium(VI)

Cited by 98 publications

References 1 publication

Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus

Terminal Nitrido and Imido Complexes of the Late Transition Metals

Photolysis of Aqueous [Os(NH3)5(N2)]2+. Photoreduction of Coordinated Dinitrogen to Hydrazine as a Model for a New Type of Artificial Photosynthesis?

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Photolysis of Aqueous [Os(NH₃)₅(N₂)]²⁺. Photoreduction of Coordinated Dinitrogen to Hydrazine as a Model for a New Type of Artificial Photosynthesis?