Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L)I5]– and cis-[{Mo6I8}(L)2I4] (L = CH3CN or 1,2,4-triazole)

Ulantikov, A.A.; Podolets, K.D.; Sukhikh, T.S.; Mironov, Y.V.; Brylev, K.A.; Gayfulin, Y.M.

doi:10.1016/j.poly.2023.116737

Polyhedron

2024

DOI: 10.1016/j.poly.2023.116737

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Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L)I5]– and cis-[{Mo6I8}(L)2I4] (L = CH3CN or 1,2,4-triazole)

A.A. Ulantikov,

K.D. Podolets,

T.S. Sukhikh

et al.

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2024

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Anionic octahedral halide molybdenum and tungsten clusters with pyrazolate ligands

Kozlova,

Berezin,

Ivanov

et al. 2024

Inorganica Chimica Acta

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Anionic octahedral halide molybdenum and tungsten clusters with pyrazolate ligands

Kozlova,

Berezin,

Ivanov

et al. 2024

Inorganica Chimica Acta

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Exploring the Frontiers of Heterometallic Systems: the {FeW₅} Octahedral Cluster Complex

Kozyreva,

Yudin,

Gaifulin

et al. 2024

Inorg. Chem.

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This research presents the first examples of heterometallic octahedral cluster complexes incorporating both 5d and 3d metals, specifically, tungsten and iron. The key compound, (TBA) 2 [FeW 5 Br 14 ] (TBA = tetrabutylammonium), exhibits selective ligand substitution reactions at the iron site when exposed to various solvents. Several {FeW 5 }-type anions, namely, [FeW 5 Br 14 ] 2− , [FeW 5 Br 13 (L)] − (L = H 2 O, DMSO, CH 3 CN), and [(FeW 5 Br 13 ) 2 O] 4− , were revealed and characterized by single-crystal X-ray diffraction analysis. The redox properties of [FeW 5 Br 14 ] 2− were studied and compared with those of [W 6 Br 14 ] 2− . Density functional theory calculations demonstrated that the bonding between Fe and W atoms is fundamentally different from the bonding between 4d (Mo−Mo) or 5d (W−W) metals in isotypic {M 6 } clusters.

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Octahedral molybdenum iodide clusters with pyrazole or pyrazolate ligands

Kozlova,

Berezin,

Kuratieva

et al. 2024

Dalton Trans.

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Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L)I5]– and cis-[{Mo6I8}(L)2I4] (L = CH3CN or 1,2,4-triazole)

Cited by 3 publications

References 65 publications

Anionic octahedral halide molybdenum and tungsten clusters with pyrazolate ligands

Anionic octahedral halide molybdenum and tungsten clusters with pyrazolate ligands

Exploring the Frontiers of Heterometallic Systems: the {FeW₅} Octahedral Cluster Complex

Octahedral molybdenum iodide clusters with pyrazole or pyrazolate ligands

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Substitution of apical iodide ligands in octahedral molybdenum cluster complexes by N-donor molecules: Synthesis and investigation of [{Mo6I8}(L)I5]– and cis-[{Mo6I8}(L)2I4] (L = CH3CN or 1,2,4-triazole)

Cited by 3 publications

References 65 publications

Anionic octahedral halide molybdenum and tungsten clusters with pyrazolate ligands

Anionic octahedral halide molybdenum and tungsten clusters with pyrazolate ligands

Exploring the Frontiers of Heterometallic Systems: the {FeW5} Octahedral Cluster Complex

Octahedral molybdenum iodide clusters with pyrazole or pyrazolate ligands

Contact Info

Product

Resources

About

Exploring the Frontiers of Heterometallic Systems: the {FeW₅} Octahedral Cluster Complex