Substitution of aqua ligands from cis‐[Pt(en)(H₂O)₂](ClO₄)₂ and cis‐[Pt(dmen)(H₂O)₂](ClO₄)₂ (en = ethylenediamine, dmen = N N′‐dimethyl ethylenediamine) by glycine in aqueous medium—a kinetic and mechanistic approach

Abstract

The kinetics of the interaction of glycine with cis- [Pt(en) [glycine], and temperature at a particular pH (4.0) where the substrate complex exists predominantly as the diaqua species and glycine as the zwitterion. The reaction was found to proceed through two consecutive steps. The first step involves the ligand-assisted anation, while the second step