Carbon dioxide and hydrocarbon gases
including methane, ethane,
propane, and produced gas (69.5/21/9.5 mol ratio of methane/ethane/propane)
were used to recover oil from rock samples collected in the Middle
Bakken (MB) target drilling zone and from a Lower Bakken Shale (LBS)
source rock. Experiments were designed to mimic the fracture-dominated
flow expected to occur during gas injection into hydraulically fractured
unconventional reservoirs such as the Bakken Petroleum System. Higher
pressures recovered oil (and heavier hydrocarbons) more efficiently
than lower pressures from both rock samples for each of the test gases
but recoveries varied dramatically with the gas used. In general,
oil recovery efficiencies from both MB and LBS rocks were the highest
with propane, followed by ethane, CO2, and produced gas,
and finally methane. Propane and ethane were the most efficient in
recovering oil hydrocarbons from the rock samples at all three pressures,
although ethane required higher pressures. Recoveries with CO2 and produced gas were low at 10.3 MPa but increased substantially
at higher pressures with the recoveries achieved at 34.5 MPa approximating
those achieved at lower pressures using propane and ethane. Finally,
methane was only capable of significant oil recoveries from MB samples
at the highest (34.5 MPa) test pressure but was not effective in mobilizing
hydrocarbons from the tighter LBS samples at any of the pressures
tested. Molar densities and the related injected gas solvent strengths
at the three test pressures had a strong influence on oil recovery
rates. For example, when molar densities of all five gases at the
three test pressures were correlated with total hydrocarbon recoveries,
linear correlation coefficients (r
2) were
significant (0.69 for 1 h oil recoveries from the MB mudrock samples
and 0.68 for the 24 h oil recoveries from the LBS shale samples).
When oil recoveries at the three test pressures were compared to the
molar densities of each individual gas, linear correlation coefficients
(r
2) ranged from 0.89 to 0.99 for the
recoveries from the MB samples, and 0.95 to >0.99 for the LBS samples
for all of the gases except propane (which gave high recoveries at
every test pressure, consistent with the fact that propane’s
molar density shows little change at the three test pressures). The
results of these laboratory studies indicate that ethane, propane,
or very rich produced gas should be capable of recovering oil from
unconventional reservoirs at significantly lower pressures than leaner
produced gas or CO2, although both produced gas and CO2 could be effective at higher pressures.