Photovoltaics (PVs, light to electricity) integrated with a thermoelectric generator (TEG, heat to electricity) has been viewed as a promising technique that can achieve high power gain and extend device lifetime, but which have rarely been applied in organic PVs. The critical temperature difference (dT c ) is a key parameter because only if the temperature difference (dT) is higher than dT c a power gain can be realized, and dT c is closely associated with device performance and application scenarios. By examining the performance of a simulated PV-TEG integrated device comprising a stateof-the-art organic solar cell and a commercial TEG at various dT s , this dT c is witnessed. An effective numerical simulation method is established to study the PV-TEG integration based on, the dT c can be perfectly reproduced and corresponding optimal p-n leg density for the TEG module to generate the highest power output at a certain dT. Integrated organic PV-TEG (OPV-TEG) devices show a lower dT c than c-SiPV-TEG devices, which, together with the lower temperature coefficient, are intrinsic advantages of OPVs for future applications. Under AM 1.5G illumination, the 1-cm 2 optimized OPV-TEG integrated device achieves a record energy conversion efficiency of 18.2%.