2014
DOI: 10.1260/0263-6174.32.7.521
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Suitability of L- and U-Curve Methods for Calculating Reasonable Adsorption Energy Distributions from Nitrogen Adsorption Isotherms

Abstract: Adsorption energy distributions (AEDs) can be calculated from measured adsorption isotherms by numerical methods upon regularization of the adsorption integral equation. The regularization solves the 'ill-posed problem' of the adsorption integral equation. In this paper, the so-called U-and L-curve methods and the modified U-curve method for estimating the optimal regularization parameter are tested with synthetic nitrogen adsorption isotherms. The isotherms are calculated from AEDs with one (minimum) to five … Show more

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Cited by 4 publications
(2 citation statements)
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“…The GDED method is similar to the L curve method and the U curve method in some aspects (Arnrich et al., 2014; Hansen, 1992; Hansen & O’Leary, 1993; Krawczyk‐Stańdo et al., 2007). These three methods are used to determine the relative weight ratio of the virtual observation (regularization parameter), and both consider the relationship between the data misfit and model roughness.…”
Section: Discussionmentioning
confidence: 99%
See 1 more Smart Citation
“…The GDED method is similar to the L curve method and the U curve method in some aspects (Arnrich et al., 2014; Hansen, 1992; Hansen & O’Leary, 1993; Krawczyk‐Stańdo et al., 2007). These three methods are used to determine the relative weight ratio of the virtual observation (regularization parameter), and both consider the relationship between the data misfit and model roughness.…”
Section: Discussionmentioning
confidence: 99%
“…Based on the Tikhonov regularization method, virtual observations must be added to the smoothing constraints, and the weight ratio of these virtual observations is often called the regularization parameter. At present, existing methods for choosing the regularization parameter mainly include the ridge method (Arthur & Robert, 1970), the generalized cross‐verification method (GCV method; Allen, 1974; Golub et al., 1979; Stone, 1974), the L curve method (Hansen, 1992; Hansen & O’Leary, 1993), and the U curve method (Arnrich et al., 2014; Krawczyk‐Stando & Rudnicki, 2007; L. Y. Wang et al., 2018).…”
Section: Introductionmentioning
confidence: 99%