Sulfobetaine-Siloxanes: A Class of Self-Destructive Surfactants
Arthur W. Snow,
Ramagopal Ananth
Abstract:The hydrolytic susceptibility of sulfobetaine-siloxane surfactants is investigated by comparison of a homologous series in this subclass of surfactants (R-(CH 2 ) 3 N + (Me) 2 (CH 2 ) 3 SO 3 − ; R = (Me 3 SiO) 3 Si-, (Me 3 SiO) 2 Si(Me)-, (Me 2 SiO) 3 -Si(Me)-) with an analogue series of oxyethylene-siloxane surfactants (R-(CH 2 ) 3 (OCH 2 CH 2 ) 10.2 OH; R = (Me 3 SiO) 3 Si-, (Me 3 SiO) 2 Si-(Me)-, (Me 2 SiO) 3 -Si(Me)-). Nuclear magnetic resonance (NMR) monitoring of these surfactants in an aqueous solution … Show more
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