2023
DOI: 10.1002/ange.202314997
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Sulfonium Cation in the Service of π‐Acid Catalysis**

Ruiping Li,
Mohammad Zafar,
David Danovich
et al.

Abstract: While still rare, cationic ligands offer much promise as tunable electron‐withdrawing ligands for π‐acid catalysis. Recently, we introduced pincer‐type sulfonium cations into the list of available strongly π‐acidic ancillary ligands. However, the M−S bond in sulfonium complexes of these ligands was found highly labile, precluding their catalytic applications. Herein we demonstrate that this obstacle can be overcome by increasing the rigidity of the sulfonium pincer scaffold. X‐ray analyses confirm that despite… Show more

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