Sulfur and Nitrogen Depositions in BULGARIA—Model Results and Observations

Abstract

Atmospheric deposition processes are of primary importance for human health, forests, agricultural lands, aquatic bodies, and ecosystems. South-East Europe is still characterized by numerous hot spots of elevated sulfur deposition, despite the reduction in European emission sources. The purpose of this study is to discuss the results from two chemical transport models and observations for wet and dry depositions of sulfur (S), reduced nitrogen (RDN) and oxidized nitrogen (OXN) in Bulgaria in 2016–2017. The spatial distribution and the domain main deposition values by EMEP MSC-W (model of the MSC-W Centre of the Co-operative Programme for Monitoring and Evaluation of the Long-range Transmissions of Air Pollutants in Europe) and BgCWFS (Bulgarian Chemical Weather Forecast System) demonstrated S wet depositions to be higher than N depositions, and identified a rural area in south-east Bulgaria as a possible hot-spot. The chemical analysis of deposition samples at three sites showed a prevalence of sulfate in the western part of the country, and prevalence of Cl and Na at a coastal site. The comparison between modeled and observed depositions demonstrated that both models captured the prevalence of S wet depositions at all sites. Better performance of BgCWFS with an average absolute value of the normalized mean bias of 16% was found.