Sulfur-doping biomass based hard carbon as high performance anode material for sodium-ion batteries

Aristote, Nkongolo Tshamala; Liu, Chang; Deng, Xinglan; Liu, Huanqing; Gao, Jingqiang; Deng, Wentao; Hou, Hongshuai; Ji, Xiaobo

doi:10.1016/j.jelechem.2022.116769

Cited by 26 publications

(12 citation statements)

References 57 publications

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“…Correspondingly, under the same conditions, the capacities of CA are 123 mA h g –1 and 100.3 mA h g –1 , and the capacities of CAB are 164.4 mA h g –1 and 108.4 mA h g –1 . Due to the outstanding electrochemical properties of the CABP material, it was compared with other similar carbon materials as indicated in Table S1 and Figure b. ,,,− Compared with similar carbon materials, both cycle performance and capacity are at the forefront, indicating the excellent sodium storage performance of CABP. To investigate the reason for the excellent cycling performance of CABP at large magnification, the effect of current density variation on the sodium storage of CABP was further investigated .…”

Section: Resultsmentioning

confidence: 99%

“…11 Recently, Aristote et al prepared sulfur-doped hard carbon materials by simple pyrolysis of sublimated sulfur and camphor-derived materials, achieving a great rate capability of 323 mA h g −1 at 80 mA g −1 . 12 Muruganantham et al prepared nitrogen-doped hard carbon materials using hexamethylenetetramine as the nitrogen source and mushroom bags as the carbon source, with excellent performance of 218 mA h g −1 after 200 cycles at 100 mA g −1 . 13 However, single-atom doping is often difficult to meet the needs of expanding the interlayer spacing and forming enough defect sites to attract Na + .…”

Section: Introductionmentioning

confidence: 99%

“…On the other hand, electronegative heteroatoms can promote the adsorption of Na + and transmission of electrons . Recently, Aristote et al prepared sulfur-doped hard carbon materials by simple pyrolysis of sublimated sulfur and camphor-derived materials, achieving a great rate capability of 323 mA h g –1 at 80 mA g –1 . Muruganantham et al prepared nitrogen-doped hard carbon materials using hexamethylenetetramine as the nitrogen source and mushroom bags as the carbon source, with excellent performance of 218 mA h g –1 after 200 cycles at 100 mA g –1 …”

Section: Introductionmentioning

confidence: 99%

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Boron–Phosphorus Codoped Coral-like Hard Carbon Anodes for Sodium Ion Storage

et al. 2023

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Hard carbon materials have the advantages of low price, environmental friendliness, and good electrical conductivity but have the disadvantages of unsatisfactory sodium storage capacity and low long-cycle stability. The use of heteroatom doping and structural design can significantly improve the sodium storage properties of carbon materials. In this paper, a boron–phosphorus doped hard carbon material (CABP) was designed by using citric acid as the carbon source. The rich pore structure of CABP also provides fast transport channels for Na+, while the efficient doping of B and P atoms can distort the graphitic layer and generate more active sites and defects. The CABP carbon material therefore exhibits excellent electrochemical properties. It can obtain pretty good capacities of 246.8 mA h g–1 after 400 cycles at 0.1 A g–1. Moreover, it was able to maintain 161.9 mA h g–1 after 5000 cycles at 5 A g–1. This work provides a new route for the facile preparation of high-performance heteroatom-doped carbon materials and an idea for the preparation of diatom-doped materials for energy storage.

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Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

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Boron–Phosphorus Codoped Coral-like Hard Carbon Anodes for Sodium Ion Storage

et al. 2023

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“…The most commonly used precursors of hard carbons are thermosetting organic compounds, including natural sources (e.g. biomasses [16]) and artificialities (e.g. resins [17]).…”

Section: Introductionmentioning

confidence: 99%

“…Biomass resources are abundant, widespread and inexpensive, but they also have distinct drawbacks such as low carbon yield, complex composition and unforeseeable impurities [18]. Compared with biomasses, resin-based precursors have unique advantages including high carbon yield, more controllable microstructure and morphology, and impurities-free [16,19,20]. Hence, resins have attracted great attentions in recent years [1,21,22].…”

Section: Introductionmentioning

confidence: 99%

Scalable synthesis of N/S co-doped hard carbon microspheres as a high-performance anode material for sodium-ion batteries

Zhang,

Huang,

Lai

et al. 2023

Nanotechnology

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Hard carbon is a promising anode material for sodium-ion batteries (SIBs) due to its abundance. However, it exhibits low reversible capacity and slow kinetics if inappropriate microstructural features are developed during synthesis. Herein, N/S co-doped phenolic resin-based hard carbon microspheres are prepared by a scalable strategy, and the electrochemical performance is assessed both in half cells and full cells. We demonstrate that the expanded interlayer spacing, the increased active sites, and the enhanced capacitive behavior result in the enhanced reversible capacity and promoted kinetics for Na+ storage. The sample with appropriate doping amount exhibits an initial charge capacity of 536.8 mAh g−1 at 50 mA g−1 and maintains 445.9 mAh g−1 after 1000 cycles at a current density of 1 A g–1 in a Na-metal half cell. Coupled with a carbon-coated Na4Fe3(PO4)2P2O7 (NFPP) cathode, the full cell exhibits a capacity of 92.5 mAh g−1 after 90 cycles, with a capacity retention of 91.6%. This work provides a facile and scalable method for synthesizing high-performance hard carbon anode materials for SIBs.

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Review: Insights on Hard Carbon Materials for Sodium‐Ion Batteries (SIBs): Synthesis – Properties – Performance Relationships

Matei Ghimbeu,

Beda,

Réty

et al. 2024

Advanced Energy Materials

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Sodium‐ion batteries (SIBs) have attracted a significant amount of interest in the past decade as a credible alternative to the lithium‐ion batteries (LIBs) widely used today. The abundance of sodium, along with the potential utilization of electrode materials without critical elements in their composition, led to the intensification of research on SIBs. Hard carbon (HC), is identified as the most suitable negative electrode for SIBs. It can be obtained by pyrolysis of eco‐friendly and renewable precursors, such as biomasses, biopolymers or synthetic polymers. Distinct HC properties can be obtained by tuning the precursors and the synthesis conditions, with a direct impact on the performance of SIBs. In this work, an in‐depth overview of how the synthesis parameters of HC affect their properties (porosity, structure, morphology, surface chemistry, and defects) is provided. Several synthesis‐property relationships are established based on a database created using extensive literature data. Moreover, HC properties are correlated with the electrochemical performance (initial Coulombic efficiency (iCE) and reversible capacity) vs. Na, in half‐cells. The Na‐ion storage mechanisms and solid electrolyte interphase (SEI) formation are discussed along with the HC performance in full‐cell devices, as well as the SIB prototypes and a short history of SIBs enterprises.

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Sulfur-doping biomass based hard carbon as high performance anode material for sodium-ion batteries

Cited by 26 publications

References 57 publications

Boron–Phosphorus Codoped Coral-like Hard Carbon Anodes for Sodium Ion Storage

Boron–Phosphorus Codoped Coral-like Hard Carbon Anodes for Sodium Ion Storage

Scalable synthesis of N/S co-doped hard carbon microspheres as a high-performance anode material for sodium-ion batteries

Review: Insights on Hard Carbon Materials for Sodium‐Ion Batteries (SIBs): Synthesis – Properties – Performance Relationships

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