A copolymer of sodium alginate (SA)-polyvinyl alcohol (PVA) was synthesized by gamma irradiation to make a hydrogel and study on its properties has been carried out. A series of 0.5% -2.0% (w/v) of SA solution and 10% (w/v) of PVA solution were prepared in separate tubes. Each of the SA solution was mixed with PVA solution, then it was irradiated with gamma ray at the doses of 30 kGy, 40 kGy, and 50 kGy (dose rate of 10 kGy/hour), respectively. The properties of hydrogels were evaluated comprising of the physical performance, gel fraction, swelling ratio, water evaporation, and pH. The results showed that increase of irradiation dose can increase the gel fraction, but increase of SA concentration can decrease the gel fraction. SA concentration of 1-2% with gamma ray irradiation dose of 30 kGy was a suitable condition to produce a good hydrogel with properties as follow, gel fraction of 75.83%-78.70%, swelling ratio of 69.12-80.14 g/ g, and maximum water evaporated of 54.21-76.41%, the pH value ranged 5.60-5.65. The hydrogels produced are suitable to be used for wound dressing, especially for wet wounds, and can be applied for two days.Keywords: Sodium alginate, polyvinyl alcohol, gamma ray irradiation, hydrogel, wound dressing ABSTRAK Kopolimer sodium alginat (SA) -polivinil alkohol (PVA) telah disintesis menggunakan irradiasi sinar gamma menjadi hidrogel, kemudian dilakukan studi sifat-sifatnya. Disiapkan satu seri larutan SA 0,5%-2,0% (b/v) dan larutan PVA 10% (b/v) dalam tabung-tabung terpisah. Masingmasing larutan SA dicampur dengan larutan PVA, kemudian diirradiasi sinar gamma dengan dosis masing-masing 30 kGy, 40 kGy, dan 50 kGy (laju dosis 10 kGy/jam). Sifat-sifat hidrogel dievaluasi, meliputi penampakan fisik, fraksi gel, rasio swelling, evaporasi air, dan pH. Hasil pengamatan menunjukkan bahwa meningkatnya dosis irradiasi dapat meningkatkan fraksi gel, tetapi meningkatnya konsentrasi SA dapat menurunkan fraksi gel. Dosis irradiasi 30 kGy dan konsentrasi 1-2% SA adalah kondisi yang sesuai untuk menghasilkan hidrogel yang baik dengan sifat-sifat: fraksi gel 75,83%-78,70%, rasio swelling 69,12-80,14 g/g, air yang menguap maksimum 54,21-76,41% dengan nilai pH pada kisaran 5,60-5,65. Hidrogel yang dihasilkan layak digunakan untuk pembalut luka, khususnya untuk luka basah, dan dapat digunakan selama 2 hari pemakaian.Kata Kunci: Sodium alginat, polivinil alkohol, irradiasi sinar gamma, hidrogel, pembalut luka