The pulsed laser deposition (PLD) technique is an excellent method to prepare single crystalline complex oxide thin ®lms. We have successfully grown ®lms for the use in HTS SQUID-devices as well as for thin ®lm optical waveguides. The Josephson junction used in the HTS SQUIDs is formed by a step edge type grain boundary junction. The step preparation is a very critical process in the SQUID preparation to achieve reproducible low 1/f noise devices. We have established a new ion beam etching process to achieve clean and steep edges in LaAlO 3 (1 0 0) substrates. The 1/f noise of SQUIDs prepared with the new method is drastically reduced. In the process of developing thin ®lm electro-optical waveguide modulators we investigated the in¯uence of different substrates on the optical and structural properties of epitaxial BaTiO 3 thin ®lms. These ®lms are grown on MgO(1 0 0), MgAl 2 O 4 (1 0 0), SrTiO 3 (1 0 0) and MgO buffered Al 2 O 3 (1 1 0 2) substrates. The waveguide losses and the refractive indices were measured with a prism coupling setup. The optical data are correlated to the results of Rutherford backscattering spectrometry/ion channeling (RBS/C), X-ray diffraction (XRD), atomic force microscopy (AFM) and transmission electron microscopy (TEM). The dielectric constant, the ferroelectric hysteresis loop and the transition temperature (ferroelectric to paraelectric state) of the BaTiO 3 thin ®lms are measured. #