We report the discovery of Zr 3 Ir as a structurally different type of unconventional noncentrosymmetric superconductor (with T c = 2.3 K), here investigated mostly via muon-spin rotation/relaxation (μSR) techniques. Its superconductivity was characterized using magnetic susceptibility, electrical resistivity, and heat capacity measurements. The low-temperature superfluid density, determined via transverse-field μSR and electronic specific heat, suggests a fully gapped superconducting state. The spontaneous magnetic fields, revealed by zero-field μSR below T c , indicate the breaking of time-reversal symmetry in Zr 3 Ir and hence the unconventional nature of its superconductivity. By using symmetry arguments and electronic-structure calculations we obtain a superconducting order parameter that is fully compatible with the experimental observations. Hence, our results clearly suggest that Zr 3 Ir represents a structurally different member of noncentrosymmetric superconductors with broken time-reversal symmetry.