In this paper, a mixed finite element method is investigated for the Maxwell's equations in Debye medium with a thermal effect. In particular, in two dimensional case, the zero order Nédélec element (Q 01 ×Q 10), the piecewise constant space Q 0 element, and the bilinear element Q 11 are used to approximate the electric field E and the polarization electric field P, the magnetic field H, and the temperature field u, respectively. With the help of the high accuracy results, mean-value technique and interpolation postprocessing approach, the convergent rate O(τ+h 2) for global superconvergence results are obtained under the time step constraint τ = O(h 1+γ), γ > 0 by using the linearized backward Euler finite element discrete scheme. At last, a numerical experiment is given to verify the theoretical analysis and the validity of our method.