Supercritical CO₂ Assisted Preparation of Supported Molybdenum Phosphide for Hydrotreating Catalysis

Abstract

Many studies in literature have reported supported metal phosphides as promising hydrotreating catalysts. The synthesis of highly dispersed metal phosphide nanoparticles is usually achieved tuning various parameters such as the nature of the phosphorous precursor or the reduction protocol. In this study, the alumina supported molybdenum phosphides were prepared following a newly developed method using supercritical fluids (SCFs) technology including several elementary steps: incipient wetness impregnation and ageing, supercritical CO2 flash‐drying, followed by hydrogen reduction. Experimental parameters allowed us modulating main characteristics of catalysts: crystallinity, reducibility, nanoparticles (NPs) mean size and size distribution. High temperature treatments (400 °C) in scCO2 media lead to the presence of heteropolyanions unlike what is observed in conventional treatment under air. Catalytic performances in selective hydrodesulfurization of methyl‐3‐thiophene, in presence of 2,3‐dimethylbut‐2‐ene, have been assessed and were improved in terms of activity or selectivity compared to MoP and CoMoS reference catalysts, respectively.

Simultaneous N2O Reduction and CO Oxidation over Pristine and Doped Molybdenum Phosphide (001) Surfaces: A Density Functional Theory Study

“…First-principles calculations have been carried out to study the hydrodenitrogenation mechanism of o -propylaniline and pyridine on MoP surfaces (001) and (010), respectively. , Deamination of aniline and N 2 reduction have been investigated over the MoP (001) surface. The MoP surfaces are also known for effectively catalyzing reactions like hydrodesulfurization , hydrodechlorination, and hydroisomerization …”