2018
DOI: 10.1039/c8ra02129e
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Supercritical CO2 drying of alginate/zinc hydrogels: a green and facile route to prepare ZnO foam structures and ZnO nanoparticles

Abstract: In the present study, we investigate a simple and effective synthetic protocol to produce zinc oxide foams by a facile solution-based method using alginate gelation.

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Cited by 15 publications
(6 citation statements)
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References 65 publications
(71 reference statements)
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“…Untreated pure ZnO aerogel exhibited a specific surface area of 152 m 2 /g. After heat treatment an expected loss of surface area was observed [2,44]. This evident surface area drop is also justified because the samples experience self-combustion during heat treatment.…”
Section: Resultsmentioning
confidence: 90%
“…Untreated pure ZnO aerogel exhibited a specific surface area of 152 m 2 /g. After heat treatment an expected loss of surface area was observed [2,44]. This evident surface area drop is also justified because the samples experience self-combustion during heat treatment.…”
Section: Resultsmentioning
confidence: 90%
“…Characteristic peaks of hydroxyl groups, due to atmospheric moisture absorption, were detected between 3332 and 3385 cm −1 . This stretching mode of O-H groups can be due to the formation of inter-and intra-molecular hydrogen bonds in the sample (Abou Oualid et al, 2017). Broad band ranging from 401 cm −1 to 530 cm −1 , highlighted the red dotted box, can be attributed to the stretching vibration of ZnO (Rohith et al, 2018).…”
Section: Fourier Transform Infrared Spectroscopy Analysis (Ftir)mentioning
confidence: 95%
“…To assist the experimental section, the density functional theory (DFT) method was employed as an additional technique for studying the complexation process. The static DFT-based optimization of the different Alg metal ion(s) complexes can shed light in their molecular structure, and also helps to nd the different nature of the metal-alginate correlations, build based on the speci c type of metal (transition metals for Cu and lanthanides metals for Ce) [14][15][16]46] The theoretical examination presented in this manuscript helps to support the experimental results done by our research group. The key objectives of this joint experimental/computational analysis can be summed up as follows:…”
Section: Introductionmentioning
confidence: 92%
“…Many works have been reported to explain the gel strengths and stability conditions induced by different metal ions [2,[7][8][9][10][11][12][13][14][15][16][17][18][19][20][21]. Alginate polymers containing trivalent cations have been recycled to formulate goldbased nanoparticles [22] and bimetallic catalysts [18].…”
Section: Introductionmentioning
confidence: 99%