2006
DOI: 10.1021/la052701l
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Superhydrophobic Surfaces Having Two-Fold Adjustable Roughness Prepared in a Single Step

Abstract: A fast and reliable method is reported for fabricating superhydrophobic surfaces. The method combines microstructure replication with polymer phase inversion and can be applied to a wide variety of polymers. This method provides a surface that contains roughness on two independently controllable levels, i.e., the microstructure level and the level of porosity stemming from the phase inversion. Both levels were optimized separately, resulting in water contact angles up to 167 degrees.

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Cited by 83 publications
(63 citation statements)
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“…These phase-separation methods are known to be rapid, simple, and cost effective processes for creating rough superhydrophobic surfaces. [18][19][20][21][22][23][24] For example, polypropylene can be dissolved in an organic solvent and spread onto a solid surface, which creates a hierarchical superhydrophobic surface after the solvent is evaporated. 25 In these processes, the solvents and temperature are important factors for controlling the surface roughness and achieving superhydrophobicity.…”
Section: -12mentioning
confidence: 99%
“…These phase-separation methods are known to be rapid, simple, and cost effective processes for creating rough superhydrophobic surfaces. [18][19][20][21][22][23][24] For example, polypropylene can be dissolved in an organic solvent and spread onto a solid surface, which creates a hierarchical superhydrophobic surface after the solvent is evaporated. 25 In these processes, the solvents and temperature are important factors for controlling the surface roughness and achieving superhydrophobicity.…”
Section: -12mentioning
confidence: 99%
“…Therefore, the large water contact angle (CA) of the lotus leaf, on the order of 160 • , is attributed to the combined effect of its covering wax and surface structure [84]. In fact, the lotus leaf presents a hierarchical surface structure that is composed of a dual-scale roughening at the micro-and nanoscale [84,85].…”
Section: Superhydrophobic Polymeric Surfacesmentioning
confidence: 99%
“…Therefore, the large water contact angle (CA) of the lotus leaf, on the order of 160°, is attributed to the combined effect of its covering wax and surface structure [84]. In fact, the lotus leaf presents a hierarchical surface structure that is composed of a dual-scale roughening at the micro-and nanoscale [84,85]. The process of mimicking the lotus leaf pattern on an artificial surface is a complex subject, because it involves precise control over surface microstructuring, while keeping the already obtained nanostructure on the surface.…”
Section: Superhydrophobic Polymeric Surfacesmentioning
confidence: 99%
“…The obtained porous PSU membranes have a surface pattern that is a negative replica of the substrate. The method could also be used to prepare a surface with two-tier hierarchical structures that feature a super-hydrophobic property [52]. Recent research studies have focused on using a poly (dimethylsiloxane) (PDMS) replica mold as the substrate instead of the silicon wafer, and on using VIPS to precipitate the polymer solution instead of the wet method.…”
Section: Phase Separation Micromoldingmentioning
confidence: 99%