Superior corrosion resistance and anti-biofouling performance via electrodeposited graphene oxide/silane composite coating with special wettability

He, Zeqiang; Cao, Hui; Zhou, Miaomiao; Jia, Wenhu; Shen, Xixun; Min, Yulin; Xu, Qing

doi:10.1016/j.surfcoat.2022.128952

Cited by 29 publications

(5 citation statements)

References 71 publications

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“…As shown in Figure 1e, the microscopic morphology of the Zn@ZMO coating may create a "gas valley" and capillary effect, which generates a steric hindrance effect, effectively inhibiting the occurrence of corrosion side reactions by excluding H 2 O molecules. 43,44 Figure 1f shows the X-ray diffraction pattern of the modified zinc anode at Zn@ZMO. Due to the excessively strong peak of metal zinc, the diffraction peak of ZnMoO 4 in the Zn@ZMO sample is not obvious.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

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In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO₄ Coating Applied for Enhancing Zinc Anode Performance

Dai,

Yun,

Lyu

et al. 2024

Langmuir

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Aqueous zinc-ion batteries (AZIBs) suffer from sharp cycling deterioration due to serious interfacial side reactions and corrosion problems on the zinc anode. Herein, an efficacious approach to construct hydrophobic ZnMoO4 coatings on Zn (denoted as Zn@ZMO) is proposed to mitigate direct contact between the zinc anode and electrolyte and enhance its cycle life. The hydrophobic ZnMoO4 layer (contact angle = 128°) with a honeycomb-like structure is prepared by an in situ liquid phase deposition method. The as-prepared ZnMoO4 coating exhibits persistent corrosion protection for Zn through 30 days of immersion in a 2 M ZnSO4 electrolyte, indicating excellent stability of the ZnMoO4 layer and ensuring its available application in AZIBs. Unique microchannels in this kind of honeycomb-like structured coating favor Zn2+ ion diffusion and ease of ion transport, especially at high current cycling. Its robust surface exclusion can effectively counter other side reactions induced by water, simultaneously. As a result, the Zn@ZMO symmetrical cell shows a remarkable cycle lifespan exceeding 2700 h at 1 mA cm–2/1 mA h cm–2, surpassing that of the bare zinc cell by more than 100 folds. At a current density of 5 A g–1, the Zn@ZMO//V2O5 cell can still achieve a specific capacity of 167.0 mA h g–1 after 500 cycles with a capacity retention rate of 88%, which demonstrates its long-term cycling stability.

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Section: ■ Results and Discussionmentioning

confidence: 99%

“…In addition, Figure S4b shows that its thickness is about 2 μm. As shown in Figure e, the microscopic morphology of the Zn@ZMO coating may create a “gas valley” and capillary effect, which generates a steric hindrance effect, effectively inhibiting the occurrence of corrosion side reactions by excluding H 2 O molecules. , …”

Section: Resultsmentioning

confidence: 99%

In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO₄ Coating Applied for Enhancing Zinc Anode Performance

Dai,

Yun,

Lyu

et al. 2024

Langmuir

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“…Q c represented coating capacitance, and Q dl represented the double-layer capacitance. 47 The Q c value could be used to evaluate the protection performance of the coating. As the Q c value was higher, there were more micropores and defects in the coating, and the corrosion resistance of the coating was worse.…”

Section: ■ Results and Discussionmentioning

confidence: 99%

“…In order to further analyze the EIS results, ZSimpWin software was used to fit the EIS data and establish the equivalent circuit (Figure c). Q c represented coating capacitance, and Q dl represented the double-layer capacitance . The Q c value could be used to evaluate the protection performance of the coating.…”

Section: Resultsmentioning

confidence: 99%

BTA-P₄₄₄₄-Lig-Functionalized MXene to Prepare Anticorrosion and Wear-Resistant Integrated Waterborne Epoxy Composite Coating

Liu,

Li,

Sun

et al. 2024

ACS Sustainable Chem. Eng.

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MXene has excellent anticorrosion and self-lubricating properties. It is widely used in the field of anticorrosion and wear resistance. However, there is a strong interaction between MXene nanosheets, which makes it easy for them to agglomerate in the coating and affects the mechanical properties of the coating. Thus, the application of MXene is limited. In this study, MXene is modified by 2,5-diaminobenzenesulfonic acid, which can reduce the aggregation of MXene in the coating. MXene is functionalized by using tetrabutylphosphorus hydroxide benzotriazole lignin composite material (BTA-P4444-Lig) with environmental protection, anticorrosion, and lubricating properties. The prepared MXene has excellent anticorrosion and lubrication properties. Functionalized MXene (f-MXene-P) is used as a filler for environmentally friendly waterborne epoxy (WEP) coatings. Electrochemical tests show that the impedance of f-MXene-P/WEP (3.91 × 107 Ω·cm2) is an order of magnitude higher than that of WEP (1.89 × 106 Ω·cm2). The maze effect of MXene and the protective film formed by BTA-P4444-Lig on the surface of Q235 steel synergistically enhance the anticorrosion performance of f-MXene-P/WEP. The friction test results show that the friction coefficient of f-MXene-P/WEP (0.068) is much lower than that of WEP (0.612). The synergistic effect of MXene and BTA-P4444-Lig with lubricating properties improves the wear resistance of f-MXene-P/WEP.

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“…Inorganic coatings have been widely used for corrosion protection on metals due to their excellent chemical stability, , environmentally friendly process, and simple construction due to their excellent wear resistance and high hardness. − However, the intrinsic hydrophilicity of silica weaken the corrosion resistance against corrosive medium. Though approaches toward hydrophobic modification have been investigated to improve the anticorrosion property, − the designed coatings still cannot meet the requirements of long-term protection. Thus, how to enhance the corrosion resistance of the silica coating and ensure stable protection has been an urgent challenge.…”

Section: Introductionmentioning

confidence: 99%

Eco-Friendly Sustainable and Responsive High-Performance Benzotriazole-Metal Organic Frameworks/Silica Composite Coating with Active/Passive Corrosion Protection on Copper

Gao,

Cao

et al. 2024

Langmuir

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Coatings with only passive protection cannot offer long-term anticorrosion on metals. Eco-friendly sustainable and responsive coating for active/passive corrosion protection is desirable to extend the service life of metals. Here, benzotriazole (BTA)-metal organic frameworks (Cu-MOFs, UiO-66) were embedded in silica (SiO 2 ) coating by one-step electrodeposition on copper. Combined with passive capability of MOFs and active protection of BTA inhibitor, the composite coating (BTA-MOF/ SiO 2 ) exhibited high and stable corrosion resistance, confirmed by microstructure characterizations and electrochemical tests. As a result, the as-prepared composite coating exhibited superhydrophobicity with a water contact angle of 154.2°. With loading of BTA-MOF in SiO 2 coating, the impedance modulus at 0.01 Hz increased by ∼10-fold and the corrosion current density decreased to 3.472 × 10 −9 A•cm −2 . Immersion and salt spray tests confirmed the long-term protection of the composite coating. The responsive release of BTA inhibitor endows the coating with a responsively anticorrosive behavior. The active-passive ability makes the coating a good candidate for protection on metals used in highly salty environments.

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Superior corrosion resistance and anti-biofouling performance via electrodeposited graphene oxide/silane composite coating with special wettability

Cited by 29 publications

References 71 publications

In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO₄ Coating Applied for Enhancing Zinc Anode Performance

In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO₄ Coating Applied for Enhancing Zinc Anode Performance

BTA-P₄₄₄₄-Lig-Functionalized MXene to Prepare Anticorrosion and Wear-Resistant Integrated Waterborne Epoxy Composite Coating

Eco-Friendly Sustainable and Responsive High-Performance Benzotriazole-Metal Organic Frameworks/Silica Composite Coating with Active/Passive Corrosion Protection on Copper

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Superior corrosion resistance and anti-biofouling performance via electrodeposited graphene oxide/silane composite coating with special wettability

Cited by 29 publications

References 71 publications

In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO4 Coating Applied for Enhancing Zinc Anode Performance

In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO4 Coating Applied for Enhancing Zinc Anode Performance

BTA-P4444-Lig-Functionalized MXene to Prepare Anticorrosion and Wear-Resistant Integrated Waterborne Epoxy Composite Coating

Eco-Friendly Sustainable and Responsive High-Performance Benzotriazole-Metal Organic Frameworks/Silica Composite Coating with Active/Passive Corrosion Protection on Copper

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Product

Resources

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In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO₄ Coating Applied for Enhancing Zinc Anode Performance

In Situ Construction of a Hydrophobic Honeycomb-like Structured ZnMoO₄ Coating Applied for Enhancing Zinc Anode Performance

BTA-P₄₄₄₄-Lig-Functionalized MXene to Prepare Anticorrosion and Wear-Resistant Integrated Waterborne Epoxy Composite Coating