Superior piezoelectricity in lead-free barium titanate piezoceramics

Cai, Enpei; Peng, Shiqiang; Liu, Qibin

doi:10.1016/j.jmat.2023.09.006

Cited by 5 publications

(1 citation statement)

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“…Materials composed of barium titanate and lead zirconate titanate have historically dominated the eld of piezoelectric ceramics [7][8][9]. However, the presence of lead in lead titanate as a wearable device is very detrimental to human health and the environment [10,11]. Therefore, it is necessary to develop lead-free piezoelectric ceramics used in smart wearable devices and electronic skin.…”

Section: Introductionmentioning

confidence: 99%

Study on the control of mechanical and electrical properties of 3D printed BTO/PDMS flexible porous composites

Hao,

Wang,

Wang

et al. 2024

Preprint

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Flexible piezoelectric functional composite materials have the advantages of strong plasticity and good surface adhesion, and show great potential in smart wearable devices, electronic skin and other applications. However, due to the complexity of traditional preparation process, high molding cost and poor air permeability, its further development is limited. Direct ink writing (DIW) 3D printing technology is a rapid prototyping technology, with higher flexibility, faster manufacturing speed and lower manufacturing costs, is widely used in metal, ceramic and composite material molding. In this work, a slurry system with polydimethylsiloxane (PDMS) as binder and Barium titanate (BTO) ceramic powder as piezoelectric filler was developed, the printing work of flexible porous BTO/PDMS composite material was completed, and DIW dual-nozzle printing technology was developed. The integrated flexible porous electrode - piezoelectric - electrode functional gradient structure composite was realized. The results show that the BTO/PDMS ink has the characteristics of shear thinning. When the nozzle diameter is 0.5 mm, the printing speed is 650 mm/min, and the BTO mass fraction is 80%, the flexible porous piezoelectric composite with high precision and complex structure is printed. By phase analysis of BTO/PDMS, it is found that the sample has the characteristic peak of BTO. The microstructure analysis shows that the surface of the sample has good structural fidelity and there are a few island-like pores in the interior. The mechanical test shows that the maximum tensile strength of the sample is 1.33 MPa, the elastic modulus is 1.72 MPa, the longitudinal piezoelectric coefficient d33 is 4.37 Pc/N, and the open circuit voltage VOC is 3.17 V. This work demonstrates a highly attractive method for forming flexible piezoelectric materials with “electrode-piezoelectric-electrode” structures, which, due to its simple operation, time and manufacturing cost savings, proposes solutions to key problems in current 3D ceramic manufacturing technologies.

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