Airborne micrometer and sub-micrometer particles produced by anthropogenic sources contaminate atmospheric air, especially in large cities where both population and industrial activities are higher leading to a reduced air quality. Recent research has pointed out particles less than 2.5 μm in diameter (PM2.5) as a potential health hazard. To address this issue stricter legislation has been put into force in order to reduce PM2.5 emissions. This paper is focused on the development of an impulsive micro-electrostatic precipitation technology for charging and removal of fine airborne particles in an economically feasible way. In the present work a compact, coaxial precipitator has been developed for possible indoor air cleaning applications. HV impulses together with dc voltage has been used for energisation of the reactor as it has been shown to enhance the precipitation efficiency. This precipitation system has been used for removal of fumes and fine airborne particles from ambient air. In addition to the experimental part, analytical work has been conducted in order to optimize the electrostatic precipitation process and to reduce its power consumption.