This paper presents the results of an investigation into the sintering behaviour of three vanadium enriched variants of T42 high-speed steel. Powders were prepared by water atomization with vanadium and carbon contents of 6-8 wt% and 2.2 -2.7 wt%, respectively. These were annealed, die pressed and sintered in vacuum. All three alloys were sintered to full density giving "as -sintered" microstructures comprising globular MC carbides dispersed in a martensitic matrix. Optimum sintering temperatures were in the range 1240 -1250ºC with lower optimum temperatures associated with higher carbon levels. Sintering characteristics are correlated with phase diagrams calculated using ThermoCalc™ software and TCFe2000 database. The implications for the design of sinterable vanadium containing high-speed steels are discussed.
Introduction: Supersolidus liquid phase sintering (SLPS) was demonstrated by Wright[1] as being the processes through which sintering of high speed steels (HSS) is carried out. In SLPS, prealloyed powders are heated to a temperature intermediate between the solidus and liquidus, Fig. 1. This method has been applied to a number of systems [2,3,4] including HSS [5,6,7,8,9].