Supported molybdenum complex on the surface of magnetite-mesoporous silica nanocomposite: new catalyst for the epoxidation of olefins

Masteri‐Farahani, Majid; Saleh, Elham

doi:10.1007/s10934-017-0529-4

Cited by 3 publications

(1 citation statement)

References 26 publications

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“…Because the core‐shell Mag‐MSNs has a high surface area, it can achieve a high dispersion of catalytic active sites and easy magnetic separation, so it is very suitable as a carrier for organic catalysis. Core‐shell Mag‐MSNs have been employed as catalysts for various types of reactions, including asymmetric hydrogenation, asymmetric Henry reaction, Olefin epoxidation, asymmetric dihydroxylation, Suzuki‐Miyaura reaction, Heck, and Sonogashira coupling reactions . The first work using core‐shell Mag‐MSNs as the organic catalyst was published by Zhao's group .…”

Section: Applications For Core‐shell Mag‐msnsmentioning

confidence: 99%

Recent Advances in the Synthesis, Surface Modifications and Applications of Core‐Shell Magnetic Mesoporous Silica Nanospheres

Zuo

et al. 2020

Chemistry An Asian Journal

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The hierarchically structured core-shell magnetic mesoporous silica nanospheres (Mag-MSNs) have attracted extensive attention, particularly in studies involving reliable preparations and diverse applications of the multifunctional nanomaterials in multi-disciplinary fields. Intriguingly, Mag-MSNs have been prepared with well-designed synthesis strategies and used as adsorbent materials, biomedicines, and in proteomics and catalysis due to their excellent magnetic responsiveness, enormous specific surface area and readiness for surface modifications. Through a carefully designed surface modification of Mag-MSNs, the performance and application prospects of the material are greatly improved. Typically, the introduction of various molecular matrices into the shell of Mag-MSNs facilitates the combination of surface modifications and magnetic separation technology. So far, as sustainable chemistry is concerned, it is important to recover the functionalized core-shell Mag-MSNs after the reaction and reuse them without losing activity. In this review, the design conceptions and the construction of core-shell Mag-MSNs are discussed. Furthermore, various surface modification approaches of core-shell Mag-MSNs are summarized, and recent applications of these functionalized nanomaterials in the fields of biomedicine, catalysis, proteomics and wastewater treatment are exemplified. 2 3 4 5 6 7 8

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Section: Applications For Core‐shell Mag‐msnsmentioning

confidence: 99%

Recent Advances in the Synthesis, Surface Modifications and Applications of Core‐Shell Magnetic Mesoporous Silica Nanospheres

Zuo

et al. 2020

Chemistry An Asian Journal

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Recent Advances in Facile Liquid Phase Epoxidation of Light Olefins over Heterogeneous Molybdenum Catalysts

Yan

Liu

Wang

et al. 2019

The Chemical Record

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Molybdenum complexes are versatile and efficient for liquid phase olefin epoxidation reactions. Rational design of catalysts is critical to achieve high atom efficiency during epoxidation processes. Although liquid phase epoxidation has been a popular topic for decades, three key issues, (a) rational control of morphology of molybdenum nanoparticles, (b) manipulating metal‐support interaction and (c) altering electronic configuration at molybdenum center remains unsolved in this area. Therefore, in this paper, we have critically revised recent research progress on heterogeneous molybdenum catalysts for facile liquid phase olefin epoxidation in terms of catalyst synthesis, surface characterization, catalytic performance and structure‐function relationship. Furthermore, plausible reaction mechanisms will be systematically discussed with the aim to provide insights into fundamental understanding on novel epoxidation chemistry.

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Incorporation of one or dual Brønsted acidic sites within the mesopores of MCM-41: Synthesis and catalytic activity in acetalization reaction

Hosseini

Masteri‐Farahani

2021

Journal of Physics and Chemistry of Solids

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Supported molybdenum complex on the surface of magnetite-mesoporous silica nanocomposite: new catalyst for the epoxidation of olefins

Cited by 3 publications

References 26 publications

Recent Advances in the Synthesis, Surface Modifications and Applications of Core‐Shell Magnetic Mesoporous Silica Nanospheres

Recent Advances in the Synthesis, Surface Modifications and Applications of Core‐Shell Magnetic Mesoporous Silica Nanospheres

Recent Advances in Facile Liquid Phase Epoxidation of Light Olefins over Heterogeneous Molybdenum Catalysts

Incorporation of one or dual Brønsted acidic sites within the mesopores of MCM-41: Synthesis and catalytic activity in acetalization reaction

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