Pervasive Social Computing is a novel collective paradigm, derived from pervasive computing, social media, social networking, social signal processing, etc. This paper reviews Pervasive Social Computing as an integrated computing environment, which promises to augment five facets of human intelligence: physical environment awareness, behavior awareness, community awareness, interaction awareness, and content awareness. Reviews of related studies are given, and their generic architectures are designed. The resulting architecture for Pervasive Social Computing is presented. A prototype is developed and examined, in order to investigate the characteristics exhibited by Pervasive Social Computing.